Make a phone call, if the service is available.
This is a conditional sentence, which is another way of saying it is a complex sentence.
Complex sentences have the form:
Conjunction x, y OR y conjunction x
"If" here is the conjunction.
The correct punctuation, therefore, would be:
If the service is available, make a phone call (with a comma); or
Make a phone call if the service is available (without a comma.)