If you are writing with a specific publisher in mind, you may want to
get their style guide before you commit to a particular style.
The common rule is, though, that everything spoken aloud is enclosed in
double quotations, while a quotation within a quotation is set apart
with single quotes.
You're correct in that italics are used for character thought, and aslo
for emphasis. Italicas are also often used for words in a
different language from the one mainly used by the characters.
Example: "Yes, I heard her," Joan testified, "she was in the washroom
and I heard her say 'I've never been to France in my life!' when Anne
asked her if she'd really been in Paris last summer."
The stinking liar, she thought to herself.
"Who lied,
mon cherie?"
Sarcasm and double entendres can also make use of the double quotation.
Example: She was "tied up" at the moment.
"My boyfriend", indeed! He was
everyone's boyfriend, it seemed.