No.
If your heart is in something, it means you have a strong belief and desire for it. I wouldn't be able to practice the bassoon four hours a day if my heart weren't in it.
If you set your mind to something, it means your are are determined to do it. Once you set your mind to it, I'm sure you'll succeed.
Neither really works for your sentence. Try: ... so she can focus completely on her studies.
(Your "waits on her hand and foot" is a good use of the idiom though!)