Unless I'm mistaken, she was back at work yesterday
Is the sentence right? Why back at work, not to work?
Both are possible.
'at work' - You are thinking of 'work' as a place, eg an office downtown somewhere.
'to work' - you are thinking of work as a task (eg write a report, sweep a floor, drive a bus)
If we are talking about Mary who stayed home sick yesterday, we normally say 'back at work'.
Best wishes, Clive