Electrical = related to electricity: electrical switching system; electrical faults
Electronic = using, based on or used in a system of operation which involves the control of electric current by various devices: an electronic gamesboard; electronic gadgets; electronic devices.
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Now for the electronic side, that consist of PCB (Printed Circuit Boards), which is covered with with smaller size components and smaller voltages and current values (.1mV to about 24V at most) as well. Mainly electronic are designed on PCBs for communications purposes (radio, cell phones, computers and many more other communication devices).
The study of electricity in semi-coductor is electronics.
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