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Chloe: Since you're on their radar I think it'll best if you went civilian.
Oliver: Unfortunately for me that means attending a Luthorcorp shareholder dinner which...
Yeah, I'd rather be shot at. I assume he's not talking about taking pictures, right?
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No, "shot at" isn't used in the sense of taking pictures. Presumably he means shot at with a gun.
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Thanks, Mr Wordy!